Study on novel structure of tris-(4,4′-dimethyl-2,2′-dipyridyl) Nickel salicylic acid boric acid, Ni(C12H12N2)3●(C7H5O3)2●(H3BO3)
نویسندگان
چکیده
A novel complex Ni(C 12 H N 2 ) 3 ●(C 7 5 O ●(H BO has been synthesized from a hydrothermal reaction and the crystal structure determined by means of single-crystal X-ray diffraction. Triclinic, P-1. a= 12.5380(13) Å, b = 13.0100(15) c 15.1490(18) α= 102.760(3)°, β= 94.480(2)°, γ= 94.540(2)°. V=2390.9(5) Å3. Z=2. R 1 =0.0661, wR 0.2128, T=293(2) K. The Ni atom is coordinated six atoms three 4,4′-dimethyl-2,2′-dipyridyl molecular. molecular stabilized O-H…O hydrogen-bonding interactions.
منابع مشابه
Unidimensional Thin Layer Chromatography of Salicylic Acid Derivatives on Boric Acid-Impregnated Plates in Drugs Studies
A unidimensional Thin Layer Chromatography system for the separation of salicylic acid and its derivatives (sulfosalicylic acid and Aspirin) has been developed. The separation was successfully using a solvent system of chloroform-methanol-water-ammonium hydroxide 120:75:6:2 (V/V) as mobile phase on TLC plates impregnated with boric acid. The method is based on different behavior of investigated...
متن کاملComplexation of Nickel Ions by Boric Acid or (Poly)borates
An experiment based on electrochemical reactions and pH monitoring was performed in which nickel ions were gradually formed by oxidation of a nickel metal electrode in a solution of boric acid. Based on the experimental results and aqueous speciation modeling, the evolution of pH showed the existence of significant nickel-boron complexation. A triborate nickel complex was postulated at high bor...
متن کاملunidimensional thin layer chromatography of salicylic acid derivatives on boric acid-impregnated plates in drugs studies
متن کامل
Reproductive toxicology. Boric acid.
Boric acid (BA), widely used for both medicinal and nonmedicinal purposes, was known to adversely affect reproduction and fertility in rodents. NIOSH, in evaluating the literature prior to writing a Criteria Document, asked NIEHS to perform an RACB study on BA to generate both structural and functional data to be used for setting exposure criteria (Fail et al., Fundam Appl Toxicol 17:225-239 [1...
متن کاملBoric Acid and Borates
Boric acid and its chemical relatives are pesticides that are derived from the element boron. Boron rarely occurs alone and is typically found in combination with other elements; common combinations are boric acid or borates.1 Unlike many pesticides which are synthetic compounds,2 boric acid and related pesticides are naturally occurring compounds.1 Boron compounds are widely found in rivers, s...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: E3S web of conferences
سال: 2021
ISSN: ['2555-0403', '2267-1242']
DOI: https://doi.org/10.1051/e3sconf/202125202069