Study on novel structure of tris-(4,4′-dimethyl-2,2′-dipyridyl) Nickel salicylic acid boric acid, Ni(C12H12N2)3●(C7H5O3)2●(H3BO3)

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چکیده

A novel complex Ni(C 12 H N 2 ) 3 ●(C 7 5 O ●(H BO has been synthesized from a hydrothermal reaction and the crystal structure determined by means of single-crystal X-ray diffraction. Triclinic, P-1. a= 12.5380(13) Å, b = 13.0100(15) c 15.1490(18) α= 102.760(3)°, β= 94.480(2)°, γ= 94.540(2)°. V=2390.9(5) Å3. Z=2. R 1 =0.0661, wR 0.2128, T=293(2) K. The Ni atom is coordinated six atoms three 4,4′-dimethyl-2,2′-dipyridyl molecular. molecular stabilized O-H…O hydrogen-bonding interactions.

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ژورنال

عنوان ژورنال: E3S web of conferences

سال: 2021

ISSN: ['2555-0403', '2267-1242']

DOI: https://doi.org/10.1051/e3sconf/202125202069